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ChemInform Abstract: Diastereoselective α-Iodination Reaction of 4-Alkenylamide Having a β-Chiral Center.

✍ Scribed by M. OKADA; O. KITAGAWA; T. HANANO; T. TAGUCHI

Book ID
101849463
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Diastereoselective α-Iodination Reaction of 4-Alkenylamide Having a β-Chiral Center.

-Optimal conditions are developed for the title reaction to give syn . alpha.-iodoalkenamides with high diastereoselectivity. The reactions can be applied to the stereoselective construction of cis-2,3-epoxy amides and 2E-conjugated dienamides such as (III) and (VIII), respectively. -

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