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ChemInform Abstract: Diastereoselective Synthesis of Functionalized 2-Methyltetrahydropyran-4-ones.

✍ Scribed by Paul A. Clarke; Philip B. Sellars; Nimesh Mistry

Publisher: John Wiley and Sons
Year: 2011
Weight: 41 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201142132

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✦ Synopsis

Abstract

A modified Maitland—Japp reaction using acetamide derivative (II) instead of an aldehyde produces dihydropyranones, which can be diastereoselectively reduced to the corresponding 2,6‐cis‐isomers.

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