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ChemInform Abstract: Diastereoselective Peracid Epoxidation: Control of the Face Selectivity via Functional Group Tuning and Proper Choice of Epoxidation Reagent.

โœ Scribed by A. J. JENSEN; K. LUTHMAN

Book ID
101863304
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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Diastereoselective peracid epoxidation:
Diastereoselective peracid epoxidation: Control of the face selectivity via functional group tuning and proper choice of epoxidation reagent
โœ Annika Jenmalm Jensen; Kristina Luthman ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Peracid epoxidation of la-f with 3-chloroperbenzoic acid (m-CPBA) and trifluoroperacetic acid (CF3CO3H) show different stereoselectivities. The olefins are substituted with two directing groups which are expected to direct the peracid to opposite faces of the alkene. Optimal face selectivities could