✦ LIBER ✦
ChemInform Abstract: Diastereoselective Hydroformylation of Acyclic Olefins: Efficient Construction of an all-anti Stereotriade Building Block for Polyketide Synthesis.
✍ Scribed by B. BREIT; S. K. ZAHN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Diastereoselective Hydroformylation of Acyclic Olefins: Efficient Construction of an all-anti Stereotriade Building Block for Polyketide Synthesis.
-The high diastereoselectivity in the formation of compound (III) is related to the preferred conformation of the acetal (I) in solution. (III) is used for the preparation of building block (VI) for the total synthesis of the macrolide antibiotic bafilomycin A 1