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ChemInform Abstract: Diastereoselective Formation of Dithioacetal Oxides from Aliphatic Sulfines under Thermodynamic Control.

✍ Scribed by Florence Corbin; Carole Alayrac; Patrick Metzner


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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πŸ“œ SIMILAR VOLUMES


Diastereoselective Formation of Dithioac
✍ Florence Corbin; Carole Alayrac; Patrick Metzner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 357 KB

Protonation of Ξ±-sulfinyl carbanions 3, resulting from the carbanions 3, at which protonation occurs under kinetic control and with retention of configuration with the selective thiophilic addition of organolithium compounds to aliphatic sulfines 2, provided dithioacetal oxides 4 (63-94% assistance