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ChemInform Abstract: Diastereoselective Darzens Condensations of α-Haloamides: Influence of Aryl Substituents on Diastereoselectivity.

✍ Scribed by Michael North; Francesca Pizzato


Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Influence of a 2-Fl
✍ M. IHARA; Y. TANAKA; N. TAKAHASHI; Y. TOKUNAGA; K. FUKUMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

Influence of a 2-Fluoro Substituent on Diastereoselectivity in the 1,3-Dipolar Cycloadditions of Nitrones. -2-Fluoro nitrones, e.g. (IIIa)-(IIIc), show reverse diastereoselectivity in the title reaction compared with 2-hydro nitrones such as (IIId)-(IIIf). It is noteworthy that no appropriate catal