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ChemInform Abstract: Diastereoselective Anomeric Oxygen to Carbon Rearrangements of Silyl Enol Ether Derivatives of Lactols.

✍ Scribed by D. J. DIXON; S. V. LEY; E. W. TATE

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Diastereoselective Anomeric Oxygen to Carbon Rearrangements of Silyl Enol Ether Derivatives of Lactols.

-As part of studies towards the anomeric oxygen to carbon rearrangements, the anomerically linked silyl enol ethers (I) are treated with SnCl 4 . Diastereoselective C-glycosidation is affected to yield the hydroxyketones (II) as main isomers. -(DIXON, D.

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✍ Darren J. Dixon; Steven V. Ley; Edward W. Tate πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

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