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ChemInform Abstract: Diastereoselective (2,3)-Wittig Rearrangement of a Tertiary Bisallylic Ether.

✍ Scribed by X. SHI; F. X. WEBSTER; J. KALLMERTEN; J. MEINWALD


Book ID
112025373
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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Diastereoselective [2,3] Wittig rearrang
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## Tertiary allylic methyl(ni-n-butylstannyl) ethers undergo transmetallation and subsequent diastereoselectve [2,3] Wittig rearrangement, wherein chiraliry transfer and olefin selectivity for the [2,3] sigmatropic event is mediated by a stereogenic center external to the sigrnatropic frnmework.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v