ChemInform Abstract: Diastereo- and Enantioselective Synthesis of Pyrrolo[1,4]benzodiazepines Through Decarboxylative Photocyclization.
β Scribed by Axel G. Griesbeck; Wolfgang Kramer; Johann Lex
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Decarboxylative Photocyclization: Synthesis of Benzopyrrolizidines and Macrocyclic Lactones. -Irradiation of potassium salts of the amino acid derivatives (I), (VII), and (IX) leads to the cyclization products (II), (VIII), and (X). Product (VIII) cyclizes with high cis diastereoselectivity, wherea