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ChemInform Abstract: Diastereo- and Enantioselective Synthesis of (+)- and (-)-cis-2-Aminocyclobutanols.

โœ Scribed by P. BISEL; E. BREITLING; A. W. FRAHM

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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Diastereo- and Enantioselective Synthesi
Diastereo- and Enantioselective Synthesis of (+)- and (โˆ’)-cis-2-Aminocyclobutanols
โœ Philippe Bisel; Elke Breitling; August Wilhelm Frahm ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 410 KB ๐Ÿ‘ 2 views

The hitherto unknown (+)-and (ฯช)-cis-2-aminocyclobutanols 6a,b and 7a,b, as well as the corresponding benzyloxycyclobutanamines 8a,b, have been synthesized by means of asymmetric reductive amination, with de values of 100% and ee values ranging from 96.9 to 99.8%. The relative cis configu-Second-gen