ChemInform Abstract: Diallylaluminum-N,N-dimethylaminoethanolate, the First Stable Allyl-Alane Suitable for Additions to Aldehydes, Ketones, and Imines.

Diallylaluminium-N,N-dimethylaminoethano

Diallylaluminium-N,N-dimethylaminoethanolate, the first stable allyl-alane suitable for additions to aldehydes, ketones and imines

✍ Herbert Schumann; Jens Kaufmann; Sebastian Dechert; Hans-Günther Schmalz 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 145 KB

The reaction of AlCl 3 with lithium-N,N-dimethylaminoethanolate (3) in a 1:1 ratio yields the corresponding organoaluminium chloride [Cl 2 Al(m-OCH 2 CH 2 NMe 2 )] 2 (1) from which the diallyl derivative [(CH 2 CHCH 2 ) 2 Al(m-OCH 2 CH 2 NMe 2 )] 2 (4) was synthesized by treatment with 2 equiv. of a