ChemInform Abstract: Dialkylzinc-Accelerated α-Trifluoromethylation of Carbonyl Compounds Catalyzed by Late-Transition-Metal Complexes.
✍ Scribed by Yuichi Tomita; Yoshimitsu Itoh; Koichi Mikami
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 39 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Acetalization of α,β-Unsaturated Carbonyl Compounds Catalyzed by Complexes of Pt(II). -Cationic diphosphine complexes of Pt(II) are sufficiently Lewis acidic to catalyze the acetalization of α,β-unsaturated carbonyl compounds (I) with ethylene glycol. In all cases tested, the Pt-complex displays co