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ChemInform Abstract: Development of Highly Chemoselective Bulky Zincate Complex, tBu4ZnLi2: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis.

✍ Scribed by Taniyuki Furuyama; Mitsuhiro Yonehara; Sho Arimoto; Minoru Kobayashi; Yotaro Matsumoto; Masanobu Uchiyama

Publisher
John Wiley and Sons
Year
2009
Weight
39 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Development of Highly Chemoselective Bul
Development of Highly Chemoselective Bulky Zincate Complex, tBu4ZnLi2: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis
✍ Taniyuki Furuyama; Mitsuhiro Yonehara; Sho Arimoto; Minoru Kobayashi; Yotaro Mat 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 444 KB

## Abstract We present full details of the unique reactivities of the newly developed dianion‐type bulky zincate, dilithium tetra‐__tert__‐butylzincate (__t__Bu~4~ZnLi~2~). With this reagent, halogen–zinc exchange reaction of variously functionalized haloaromatics and anionic polymerization of __N_