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ChemInform Abstract: Development and Synthetic Application of Epoxysilane Rearrangement

✍ Scribed by Michiko Sasaki

Publisher
John Wiley and Sons
Year
2008
Weight
15 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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Organoaluminum-Promoted Rearrangement of Epoxysilanes to Ξ±-Silylaldehydes. -Selective rearrangement of epoxysilanes to Ξ±silylaldehydes is achieved with high efficiency by using the exceptionally bulky Lewis acid MABR as s stoichiometric reagent. Rearrangement of deuterated derivatives (III) and (V)