ChemInform Abstract: “Design” of Boron-Based Compounds as Pro-Nucleophiles and Co-Catalysts for Indium(I)-Catalyzed Allyl Transfer to Various Csp3-Type Electrophiles.

✍ Scribed by Hai Thanh Dao; Uwe Schneider; Shu Kobayashi

• Book ID: 102070544
• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 38 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201152035

✦ Synopsis

Abstract

An improved methodology for the indium(I)‐catalyzed allylation of acetals and ethers, through combination of allyl boronate as pro‐nucleophile with a commercially available borinic ester as co‐catalyst, is reported.