ChemInform Abstract: Design and Preparation of a Chiral Ligand Based on a Pseudorotaxane Skeleton: Application to Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides.
β Scribed by Gaku Hattori; Tetsuharu Hori; Yoshihiro Miyake; Yoshiaki Nishibayashi
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 33 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Design, Synthesis, and Application of a C 2 Symmetric Chiral Ligand for Enantioselective Conjugate Addition of Organolithium to Ξ±,Ξ²-Unsaturated Aldimine. -Acyclic aldimines (I), cyclic aldimines (IV), and naphthaldehyde imines like (VI) undergo enantioselective conjugate additions to organolithiums