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ChemInform Abstract: Deprotonation of Oxazolinyloxiranes. Formation of Substituted Acyloxiranes.

✍ Scribed by Saverio Florio; Vito Capriati; Serena Di Martino; Alessandro Abbotto

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199925090

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✦ Synopsis

Deprotonation of Oxazolinyloxiranes. Formation of Substituted Acyloxiranes. -In the presence of sBuLi/TMEDA oxazolinyloxiranes undergo rapid and smooth deprotonation. Subsequent trapping with electrophiles leads to highly substituted oxiranes which can be easily deblocked to acyloxiranes. This represents a novel and efficient method to prepare substituted acyloxiranes which are synthetically useful synthons.

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