ChemInform Abstract: Dephosphonylation of β-Keto Phosphonates with LiAlH4.
✍ Scribed by J. E. HONG; W. S. SHIN; W. B. JANG; D. Y. OH
- Book ID
- 112034935
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Alkylation of [5-keto phosphonates is performed by teatment of 15-keto phosphonates with n-BuLi, followed by addition of alkyl halides. The acquired c~fully substituted 13-keto phosphonates are dephosphonylated by treatment of the lithium enolates with LiAIH4, followed by quenching with aqueous H2SO
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