Syntheses of the spiro nucleosides 2Ј-deoxyhydantocidin 3a and its 1Ј-epimer 3b are described. The newly developed route involves a Horner-Wadsworth-Emmons condensation of the phosphonate 16 with the erythrose derivative 15 affording a mixture of six isomers which was fully assigned by
ChemInform Abstract: Deoxyhydantocidin: Synthesis by Base-Catalyzed Spiro Cyclization and Interconversion with the 1′-Epimer.
✍ Scribed by Annabelle Renard; Mitsuharu Kotera; Marie-Christine Brochier; Jean Lhomme
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 33 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v