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ChemInform Abstract: Dealkylation of Alkyl and Aryl Ethers with AlCl3—NaI in the Absence of Solvent.

✍ Scribed by Mehran Ghiaci; Jila Asghari

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Dealkylation of Alkyl and Aryl Ethers with AlCl 3 -NaI in the Absence of Solvent.

-The method is not suitable for the conversion of cholesteryl methyl ether to cholesterol and for the demethylation of 1-methoxynaphthalene which sublimes under the reaction conditions. A further disadvantage could be the formation of small amounts of iodine which can react with sensitive functional groups. Thus, allyl phenyl ether gives a mixture of products under the reaction conditions.

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