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ChemInform Abstract: DBU-MeOH Promoted One-Pot Stereoselective γ-Functionalization of 1,3-Dicarbonyls: Reactivity of β-Ketoamides Towards α,β-Unsaturated Aldehydes.

✍ Scribed by Emmanuelle Charonnet; Marie-Helene Filippini; Jean Rodriguez

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Novel DBU—MeOH-Prom
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## Abstract A new cascade pathway viable for Knoevenagel chemistry that involves the coupling between 1,3‐dicarbonyl systems and α,β,γ,δ‐unsaturated aldehydes has been developed. The process comprises the combination of a classic aldol‐type condensation and a rare spontaneous metal‐free cycloisomer