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ChemInform Abstract: D-Xylose Derived Oxazolidin-2-ones as Chiral Auxiliaries in Stereoselective Alkylations.

✍ Scribed by P. KOELL; A LUETZEN


Book ID
112034571
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
27
Category
Article
ISSN
0931-7597

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Chiral N-acylated oxazolidin-2-ones readily available from D-xylose have been demonstrated to undergo highly diastereoselective acylation reactions via their lithium imide enolates to afford 13-keto imides. These are easily purified and exhibit surprisingly high stability towards epimerization. The

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v