ChemInform Abstract: D-Xylose Derived Oxazolidin-2-ones as Chiral Auxiliaries in Stereoselective Alkylations.
β Scribed by P. KOELL; A LUETZEN
- Book ID
- 112034571
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Chiral N-acylated oxazolidin-2-ones readily available from D-xylose have been demonstrated to undergo highly diastereoselective acylation reactions via their lithium imide enolates to afford 13-keto imides. These are easily purified and exhibit surprisingly high stability towards epimerization. The
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