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ChemInform Abstract: Cyclopropanation of a β-Himachalene Monoepoxide Derivative.

✍ Scribed by E. LASSABA; A. BENHARREF; M. GIORGI; M. PIERROT

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diastereoselective
ChemInform Abstract: Diastereoselective Cyclopropanation of α,β-Unsaturated Acetals of a Novel Camphor-Derived Chiral Auxiliary.
✍ Perry T. Kaye; Warner E. Molema 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Diastereoselective Cyclopropanation of α,β-Unsaturated Acetals of a Novel Camphor-Derived Chiral Auxiliary. -2-exo-3-exo-Dihydroxybornane-10-sulfonate (III) proves to be a highly efficient chiral auxiliary for the asymmetric Simmons-Smith cyclopropanation of α,βunsaturated acetal derivatives [cf.