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ChemInform Abstract: Cycloaddition of CO2 and CS2 to a Cyclic Phosphazene.

โœ Scribed by Thomas von Criegern; Kurt Polborn; Alfred Schmidpeter


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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Cycloaddition of CO2 and CS2 to a cyclic
โœ Thomas von Criegern; Kurt Polborn; Alfred Schmidpeter ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 164 KB ๐Ÿ‘ 2 views

## Carbon dioxide and carbon disulfide give crystalline cycloadducts with the phosphazene bond of a 1,2k 5 -azaphosphole. The CO 2 -adduct fully dissociates in solution, the CS 2 -adduct on short heating only to a small part. On longer heating, the latter rearranges in two successive 1,3-shifts to