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ChemInform Abstract: Cyclizations and Rearrangements of Samarium Diiodide Generated Vinyl Radicals.

โœ Scribed by L. CAPELLA; P. C. MONTEVECCHI; M. L. NAVACCHIA

Book ID
112029818
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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โœ T. SKRYDSTRUP; D. MAZEAS; M. ELMOUCHIR; G. DOISNEAU; C. RICHE; A. CHIARONI; J.-M ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

1,2-cis-C-Glycoside Synthesis by Samarium Diiodide-Promoted Radical Cyclizations. -Glucosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C-2 OH position are quickly reduced by SmI2 in the absence of a cosolvent leading to the stereospecific synthesis of 1,2-cis-Cglycosides s