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ChemInform Abstract: Cyclization of 3-Aminoacrylates — Total Synthesis of Pumiliotoxin C and Related Stereoisomeric Compounds.

✍ Scribed by T. RIECHERS; H. C. KREBS; R. WARTCHOW; G. HABERMEHL

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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Cyclization of 3-Aminoacrylates – Total
Cyclization of 3-Aminoacrylates – Total Synthesis of Pumiliotoxin C and Related Stereoisomeric Compounds
✍ Torsten Riechers; Hans Christoph Krebs; Rudolf Wartchow; Gerhard Habermehl 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB 👁 2 views

A method is described for the synthesis of pumiliotoxin C acrylates was transformed into bromide using the tosylate method. Cyclization of the bromides led to unsaturated (1a) and related stereoisomeric compounds 1c-1f. Starting from (+)-or (-)-3-methylcyclohexanone (6a,b), the oxo esters quinoline