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ChemInform Abstract: Cyclization of 1,2-Disilacyclohexa-3,5-dienes Initiated by Electron Transfer Reactions with TCNE.

✍ Scribed by Kunio Mochida; Hiromi Shimizu; Masato Nanjo


Publisher
John Wiley and Sons
Year
2001
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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The 9,10-dicyanoanthracene-photosensitized (DCA-photosensitized) electron-transfer reaction of 1-isopropylidene-2methylene-3,3-diphenylcyclobutane (3) gives a mixture of the [4 + 4] DCA adduct (5) and two [4 + 4] cyclodimers Scheme 1