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ChemInform Abstract: Cyclic SiS2: A New Perspective on the Walsh Rules.

✍ Scribed by Leonie Anna Mueck; Valerio Lattanzi; Sven Thorwirth; Michael C. McCarthy; Juergen Gauss

Book ID: 112047355
Publisher: John Wiley and Sons
Year: 2012
Weight: 19 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201230002

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Intramolecular homolytic substitution reactions at silicon to generate cyclic five-membered alkoxysilanes need a trimethylstannyl substituent at the silicon as leaving group, e.g. (IV), or additional trimethylsilyl groups, e.g. (V), to get high yields. Since a tin radical is liberated in this new mi