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ChemInform Abstract: Cyclic O,N-Acetals

โœ Scribed by C. Kibayashi; N. Yamazaki

Publisher
John Wiley and Sons
Year
2009
Weight
15 KB
Volume
40
Category
Article
ISSN
0931-7597

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Catalytic, Enantioselective Alkylations of N,O-Acetals. -The first high-yielding (73-93%) asymmetric alkylations (e.e. up to 96%) of racemic hemiacetals of type (I) with nucleophiles (II) or (V) using a chiral Cu(I)-based catalyst are presented. Several N-protecting sulfonyl groups are tested with