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ChemInform Abstract: Cyclic Aryleneazachalcogenenes. Part 15. Substituted 1,3,2,4-Benzodithiadiazines: Novel Derivatives, By-Products, and Intermediates.

โœ Scribed by Alexander Yu. Makarov; Irina Yu. Bagryanskaya; Yuri V. Gatilov; Tatiana Mikhalina; Makhmut M. Shakirov; Lyudmila N. Shchegoleva; Andrey V. Zibarev


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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Substituted 1,3,2,4-benzodithiadiazines:
โœ Alexander Yu. Makarov; Irina Yu. Bagryanskaya; Yuri V. Gatilov; Tatiana V. Mikha ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 296 KB

cycle. The distortion of the planar geometry of some compounds 1 is interpreted in terms of a pseudo-Jahn-Teller effect as the result of ฯ€-highest occupied molecular orbital (HOMO) ฯƒ\*-(LUMO) lowest unoccupied molecular orbital + 1 mixing in a planar conformation. The 2p compound is the first struct