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ChemInform Abstract: Crystallographic Data of New Ternary La2Sb-Type GdScSi, GdScGe, TbScGe Compounds, Ti5Ga4-Type LnScSi (Ln: Tb—Tm) and LnScGe (Ln: Dy—Tm) Compounds.

✍ Scribed by A. V. MOROZKIN; YU. D. SEROPEGIN; V. K. PORTNOY; A. V. LEONOV; I. A. SVIRIDOV

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 structure structure (solids and liquids) D 2000

47 -014

Crystallographic Data of New Ternary La 2 Sb-Type GdScSi, GdScGe, TbScGe Compounds, Ti 5 Ga 4 -Type LnScSi (Ln: Tb-Tm) and LnScGe (Ln: Dy-Tm) Compounds.

-Twelve new silicides and germanides of title are prepared by arc melting of the elements and subsequent annealing at 1070 K (200 h). Their structures are determined by powder XRD. The compounds GdScSi, GdScGe, and TbScGe crystallize in the tetragonal La 2 Sb type structure, space group I4/mmm. LnScSi with Ln: Tb, Dy, Ho, Er, Tm and LnScGe with Ln: Dy, Ho, Er, and Tm crystallize in the hexagonal Ti 5 Ga 4 type structure, space group P6 3 /mcm.The Ti 5 Ga 4 type structure appears to be the high-temp. modification, while the La 2 Sb type is the low-temp. form of the compounds. -(MOROZKIN, A.

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