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ChemInform Abstract: Crystal Structure of [PhMe3N]4[Pb3Br10].

✍ Scribed by Th. Wiest; R. Blachnik; H. Reuter

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

structure (solids and liquids) D 2000 52 -013 Crystal Structure of [PhMe 3 N] 4 [Pb 3 Br 10 ].

-The title compound (III) crystallizes in the monoclinic space group P2 1 /c with Z = 2 (single crystal XRD). The structure consists of a two-dimensional anionic partial structure of Cs 4 Mg 3 F 10 type formed by sharing of four corners of each [Pb 3 Br 8 Br 4/2 ] 4- anion, which in turn consists of three face-sharing PbBr 6 octahedra.

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