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ChemInform Abstract: Crystal Structure of Na4HP3O10×H2O.

✍ Scribed by N. KINDLER; M. JANSEN

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

1997 structure structure (solids and liquids) D 2000 19 -003 Crystal Structure of Na4HP3O10•H2O. -Single crystals of the title compound are precipitated from a 0.4 M aqueous Na5P3O10 solution (pH 4, adjusted with HOAc; addn. of MeOH). Na4HP3O10•H2O crystallizes in the orthorhombic space group Pbcn with Z = 4. The structure consists of alternating layers of triphosphate anions and sodium cations. The triphosphate groups have C2 site symmetry and are linked by strong O-H bonds (244 pm). -(KINDLER, N.;

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