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ChemInform Abstract: Crystal Structure and Properties of Some Filled and Unfilled Skutterudites: GdFe4P12, SmFe4P12, NdFe4As12, Eu0.54Co4Sb12, Fe0.5Ni0.5P3, CoP3, and NiP3.

โœ Scribed by Wolfgang Jeitschko; Aloys J. Foecker; Dirk Paschke; Martin V. Dewalsky; Ch. B. H. Evers; Bernd Kuennen; Arne Lang; Gunter Kotzyba; Ute Ch. Rodewald; Manfred H. Moeller


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
31
Category
Article
ISSN
0931-7597

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Crystal Structure and Properties of Some
โœ Wolfgang Jeitschko; Aloys J. Foecker; Dirk Paschke; Martin V. Dewalsky; Ch. B. H ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 274 KB ๐Ÿ‘ 1 views

The new cubic compound Fe 0.5 Ni 0.5 P 3 (a = 775.29(5) pm) as well as the known compounds CoP 3 and NiP 3 were synthesized from the elemental components using tin as a flux. Their skutterudite (CoAs 3 ) type structures were refined from single-crystal X-ray data. The new compound GdFe 4 P 12 was pr