ChemInform Abstract: Crystal Engineering in [(12-crown-4)2Na][Cd(SCN)3]: First Example of an Anionic Cadmium Thiocyanate Coordination Solid with a Sandwich [(12-crown-4)2Na]+ Cation as Spacer/Controller, Resulting in a Hexagonal Arrangement of Antiparallel Zigzag [Cd(SCN)3-]∞ Chains.
✍ Scribed by H. ZHANG; X. WANG; K. ZHANG; B. K. TEO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1998 structure structure (solids and liquids) D 2000
39 -002
Crystal Engineering in [(12-crown-4) 2 Na][Cd(SCN) 3 ]: First Example of an Anionic Cadmium Thiocyanate Coordination Solid with a Sandwich [(12-crown-4) 2 Na] + Cation as Spacer/Controller, Resulting in a Hexagonal Arrangement of Antiparallel Zigzag [Cd(SCN) 3 -]∞ Chains.
-Compound (IV) is the first example of an anionic Cd thiocyanate coordination solid in which a sandwich [(12-crown-4) 2 Na] + monocation serves as the spacer/controller, giving rise to a hexagonal array of antiparallel infinite zigzag [Cd(SCN) -3 ]∞ chains with the cations occupying the triangular channels. The single crystal XRD shows a monoclinic unit cell of P2 1 /n space group symmetry with Z = 4. -(ZHANG, H.;