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ChemInform Abstract: Crown Ethers: The Search for Selective Ion Ligating Agents

✍ Scribed by J. S. BRADSHAW; R. M. IZATT

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
28
Category
Article
ISSN
0931-7597

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Tuning the Structure of Lariat Crown Eth
Tuning the Structure of Lariat Crown Ethers for Ion-Selective Electrodes: Significant Shifts in Sodium/Potassium Selectivity
✍ J.β€…Christopher Ball; Johnβ€…R. Allen; Jong-Yol Ryu; Sarah Vickery; Lawrence Cullen πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 334 KB πŸ‘ 1 views

Lariat crown ethers (LCEs) offer the ability to bind selectively alkali metal ions. The presence of a coordinating functionality in the sidearm chain provides a means to further tune the selectivity of LCEs. A series of four LCEs based on a 15-crown-5 structural motif were synthesized with variation