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ChemInform Abstract: Cross Metathesis of the Amino Acid Homoallylglycine.

✍ Scribed by S. E. GIBSON; V. C. GIBSON; S. P. KEEN

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199743209

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✦ Synopsis

Cross Metathesis of the Amino Acid Homoallylglycine.

-Ruthenium-catalyzed reaction of protected homoallylglycine derivatives (I) with olefins (II) provides cross metathesis products (III) (10 examples) in acceptable synthetic yields. The reaction is independent of the amino acid protecting groups as well as of the nature of the olefin. -(GIBSON, S. E.; GIBSON, V.

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