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ChemInform Abstract: Cp* Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry.

โœ Scribed by Meng Zhou; Nathan D. Schley; Robert H. Crabtree

Publisher
John Wiley and Sons
Year
2011
Weight
34 KB
Volume
42
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

The hydroxylation of cycloalkanes (I) and (III) proceeds smoothly in the presence of an Irโ€”Cp* catalyst to give the product cycloalkanols (II) and (IV), resp., with retention of stereoselectivity.

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ChemInform Abstract: Hydroxylation of Alkanes by Molecular Oxygen with Dinuclear Fe(II) Macrocyclic Complexes as Catalysts.
โœ Z. WANG; A. E. MARTELL; R. J. MOTEKAITIS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 1 views

Hydroxylation of Alkanes by Molecular Oxygen with Dinuclear Fe(II) Macrocyclic Complexes as Catalysts. -The 24-membered macrocyclic iron complex, RBP, is found to be a better catalyst for the oxidation of alkanes (I) and (IV) than the 30-membered macrocycle RBB. H 2 S acts as 2-electron reductant. -