ChemInform Abstract: Coupling of Fluoroform with Aldehydes Using an Electrogenerated Base.

✍ Scribed by R. BARHDADI; M. TROUPEL; J. PERICHON

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 32 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199842091

✦ Synopsis

Coupling of Fluoroform with Aldehydes Using an Electrogenerated

Base.

-Trifluoromethylated alcohols, e.g. (III), are easily obtained in a one-pot electroreaction of CF 3 H (II) with aldehydes, like (I) or an alkyl halide (IV). The reaction conditions are also used for the synthesis of product (VII).