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ChemInform Abstract: Copper(I) Chloride-Mediated Oxidative Coupling of Alkenyltrialkylstannyl Functions: Efficient Stereocontrolled Syntheses of Uniquely Functionalized Conjugated Diene Systems.

✍ Scribed by E. PIERS; E. J. MCEACHERN; M. A. ROMERO; P. L. GLADSTONE


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Copper(I) Chloride-Mediated Oxidative Coupling of Alkenyltrialkylstannyl Functions: Efficient Stereocontrolled Syntheses of Uniquely Functionalized Conjugated Diene Systems.

-The new coupling method results in the assembly of structurally novel, highly functionalized conjugated diene systems via the stereospecific coupling of vinylic carbons bearing the stannyl function. The reaction is efficient and tolerates a variety of functional groups. -(PIERS, E.; MCEACHERN, E.