ChemInform Abstract: Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts.

✍ Scribed by Cheng-Pan Zhang; Zong-Ling Wang; Qing-Yun Chen; Chun-Tao Zhang; Yu-Cheng Gu; Ji-Chang Xiao

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 26 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201120102

✦ Synopsis

Abstract

Based on the observation that substrate (I) can be reduced by metals, a convenient synthesis of trifluoromethylated aryl and hetaryl derivatives from the corresponding iodides is developed.