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ChemInform Abstract: Copper-Free Sonogashira Coupling Reaction Using a trans-Spanning 1,2-Bis(2-thienylethynyl)benzene Ligand.

✍ Scribed by Shingo Atobe; Motohiro Sonoda; Yuki Suzuki; Hiroyuki Shinohara; Takuya Yamamoto; Akiya Ogawa

No coin nor oath required. For personal study only.

✦ Synopsis

The coupling reaction of aryl halides (I) with terminal acetylenes (II) proceeds in the presence of diethynylbenzene as a trans‐bidentatable ligand.

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