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ChemInform Abstract: Copper-Catalyzed Asymmetric Conjugate Addition of Trialkylaluminum Reagents to Trisubstituted Enones: Construction of Chiral Quaternary Centers.

✍ Scribed by Magali Vuagnoux-d'Augustin; Alexandre Alexakis


Publisher
John Wiley and Sons
Year
2008
Weight
66 KB
Volume
39
Category
Article
ISSN
0931-7597

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Scheme 1. Transmetalation of phenylboronic acid to triethylaluminum. CuTC = copper thiophencarboxylate. Scheme 2. I/Li-exchange-Li/Al-transmetalation sequence.