ChemInform Abstract: Cooperative Catalysis for the First Asymmetric Formal [3 + 2] Cycloaddition Reaction of Isocyanoacetates to α,β-Unsaturated Ketones.
✍ Scribed by Carlos Arroniz; Alberto Gil-Gonzalez; Vladislav Semak; Carmen Escolano; Joan Bosch; Mercedes Amat
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 28 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The title reaction represents a new method for the easy and rapid construction of enantioenriched 2,3‐dihydropyrroles from α,β‐unsaturated ketones.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Diverse Cycloaddition Chemistry Leading to Overall Michael Addition in the Reactions of 1,1-Bis(dimethylamino)-2,2-difluoroethene with α,β-Unsaturated Aldehydes, Ketones, Esters, and Nitriles. -The freshly prepared difluoro ketene aminal (I) reacts with α,β-unsaturated aldehydes or ketones via [4 +