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ChemInform Abstract: Conversion of Hydroxy Nitriles to Lactones Using Rhodococcus rhodochrous Whole Cells.

✍ Scribed by S. K. TAYLOR; N. H. CHMIEL; L. J. SIMONS; J. R. VYVYAN

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Conversion of Hydroxy Nitriles to Lactones Using Rhodococcus rhodochrous Whole Cells.

-Lactones are synthesized from hydroxy nitriles in one step under very mild conditions by microbial hydrolysis and lactonization using R. rhodochrous whole cells. Younger, actively growing cell cultures afford a modest enantioselectivity in the formation of (R)-(II) at the expense of the chemical yield. In contrast, older, resting cells provide very good yields of the lactones, e.g. rac. (II), with little or no enantioselectivity. -

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