ChemInform Abstract: Conversion of Azides to Diazo Compounds.

✍ Scribed by G. B. FEIGELSON

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 26 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199820095

✦ Synopsis

1998 azo compounds

azo compounds (diazo compounds, triazenes etc.) (acyclic compounds) P 0090

20 -095

Conversion of Azides to Diazo Compounds.

-Reaction of azides (I) with triphenylphosphine under Staudinger conditions followed by treatment of the resulting iminophosphoranes with base and a nitrosating agent provides the targets (III) in moderate yields. -(FEIGELSON, G.