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ChemInform Abstract: Conversion of Acid Chloride into Homoallylic Alcohol via Allylic C—H Bond Activation of Alkene with a Zirconocene Complex.

✍ Scribed by Kazuya Fujita; Hideki Yorimitsu; Hiroshi Shinokubo; Seijiro Matsubara; Koichiro Oshima


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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Regioselective Alkylation of 2-Phenylpyridines with Terminal Alkenes via C-H Bond Activation by a Rhodium Catalyst. -Rh(I)-catalyzed reaction of 2-phenylpyridines with terminal alkenes provides regioselectively or even exclusively ortho-alkylated products of the anti-Markovnikov-type (cf. (III), (VI