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ChemInform Abstract: Conversion of 1,1,2-Trichlorotrifluoroethane to 1,1,1-Trichlorotrifluoroethane and 1,1-Dichlorotetrafluoroethane over Aluminum-Based Catalysts.

✍ Scribed by H. Bozorgzadeh; E. Kemnitz; M. Nickkho-Amiry; T. Skapin; J. M. Winfield


Publisher
John Wiley and Sons
Year
2001
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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Products, rate constants and mechanisms
✍ Ester Marotta; Cristina Paradisi πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 159 KB

## Abstract The gas‐phase ion chemistry of 1,1,1‐ and 1,1,2‐trichlorotrifluoroethane was investigated with an ion trap mass spectrometer. Following electron ionization both compounds (M) fragment to [M βˆ’ Cl]^+^, CX~3~^+^, CX~2~^+^, CX^+^ (X = F and/or Cl) and Cl^+^. The reactivity of each of these