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ChemInform Abstract: Convenient Two-Step Conversion of Lactones into Cyclic Ethers.

โœ Scribed by M. C. HANSEN; X. VERDAGUER; S. L. BUCHWALD

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: An Efficient and St
ChemInform Abstract: An Efficient and Stereoselective Conversion of Lactones to Substituted Cyclic Ethers.
โœ H. YODA; M. MIZUTANI; K. TAKABE ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 38 KB ๐Ÿ‘ 2 views

An Efficient and Stereoselective Conversion of Lactones to Substituted Cyclic Ethers. -Cerium(III) chloride assisted addition of Grignard reagents to lactones and following BF 3 โ€ขOEt 2 mediated deoxygenation of the resulting hemiketals [cf. (III)] with triethylsilane provides a general route to cycl