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ChemInform Abstract: Controlling Factors Governing Catalytic Process: Asymmetric Allylation Reaction Promoted by BINOL-Zr(IV) Catalyst with Synergetic Reagent.

✍ Scribed by C.-M. YU; H.-S. CHOI; W.-H. JUNG; H.-J. KIM; J.-K. LEE


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


In continuation of earlier work the enantioselective allylation of aldehydes, e.g. (I), is investigated. It is noteworthy that iPr-S-BEt2 is a synergetic reagent, which finally gives optimal chemical yields and enantioselec-